[Omeo33] Art 1041 - J Mol Liq, 2009, 146 (3), 122-126

Gino Santini g.santini a ismo.it
Mer 26 Ago 2009 12:34:31 CEST


Conductometric and pHmetric titrations of Extremely Diluted Solutions  
using HCl solutions as titrant: A molecular model
C.M. Cacace, L. Elia, V. Elia and M. Niccoli

We carried out conductometric titrations of Extremely Diluted  
Solutions (EDS), obtained through an iterative process of successive  
dilutions and agitations. The aim of our investigations was to gain  
information on whether the agitation/dilution processes could produce  
non-equilibrium changes in the supramolecular structure of water and  
aqueous solutions. The titrations were performed by adding HCl  
solutions at concentrations between 1·10− 4 and 1·10− 3 M. The  
measurements evidenced some relevant differences between the EDS and  
the water solvent. Such results were interpreted by considering the  
interactions that can take place between the H+ ions and some  
hypothesized molecular aggregates of water molecules, i.e. dissipative  
structures.

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