[Omeo33] Art 1041 - J Mol Liq, 2009, 146 (3), 122-126
Gino Santini
g.santini a ismo.it
Mer 26 Ago 2009 12:34:31 CEST
Conductometric and pHmetric titrations of Extremely Diluted Solutions
using HCl solutions as titrant: A molecular model
C.M. Cacace, L. Elia, V. Elia and M. Niccoli
We carried out conductometric titrations of Extremely Diluted
Solutions (EDS), obtained through an iterative process of successive
dilutions and agitations. The aim of our investigations was to gain
information on whether the agitation/dilution processes could produce
non-equilibrium changes in the supramolecular structure of water and
aqueous solutions. The titrations were performed by adding HCl
solutions at concentrations between 1·10− 4 and 1·10− 3 M. The
measurements evidenced some relevant differences between the EDS and
the water solvent. Such results were interpreted by considering the
interactions that can take place between the H+ ions and some
hypothesized molecular aggregates of water molecules, i.e. dissipative
structures.
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